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In addition to conventional relaxation dispersion studies, Fast Field Cycling NMR extends its capabilities to advanced analytical approaches that further broaden its range of applications. Among these, Overhauser Dynamic Nuclear Polarization (DNP) and FFC-based diffusion measurements represent powerful methodologies for investigating molecular dynamics and transport phenomena.

Use

FFC NMR diffusion measurements

DNP Overhouser Dynamic Nuclear Polarization

Literature Reference

FFC NMR diffusion measurements

"Intermolecular Spin Relaxation and Translation Diffusion in Liquids and Polymer Melts: Insight from Field-Cycling 1H NMR Relaxometry"

R. Meier, D. Kruk, A. Ernst, E. A. Rössler ChemPhysChem 2013, 14, 3071–3081

"Translational and rotational diffusion of glycerol by means of field cycling 1H NMR relaxometry"

D. Kruk, R. Meier, E. A. Rössler J. Phys. Chem. B 2011, 115, 951–957

"Perspectives of Deuteron Field-Cycling NMR Relaxometry for Probing Molecular Dynamics in Soft Matter"

M. Flämig, M. Becher, M. Hofmann, T. Körber, B. Kresse, A. F. Privalov, D. Kruk, F. Fujara, E. A. Rössler J. Phys. Chem. B 2016, 120, 7754–7766

"Self-diffusion studies by intra- and intermolecular spin-lattice relaxometry using field-cycling: Liquids, plastic crystals, porous media, and polymer segments"

R. Kimmich, N. Fatkullin Prog. Nucl. Magn. Reson. Spectrosc. 2017, 101, 8–50

"Nuclear magnetic resonance relaxometry as a method of measuring translational diffusion coefficients in liquids"

D. Kruk, R. Meier, E. A. Rössler Phys. Rev. E 2012, 85, 020201

"Novel application of NMR relaxometry in studies of diffusion in virgin rape oil"

A. Rachocki, J. Tritt-Goc Food Chem. 2014, 152, 94–99

"Determining diffusion coefficients of ionic liquids by means of field cycling nuclear magnetic resonance relaxometry"

D. Kruk, R. Meier, A. Rachocki, A. Korpała, R. K. Singh, E. A. Rössler J. Chem. Phys. 2014, 140, 244509

"Combining 7Li NMR field-cycling relaxometry and stimulated-echo experiments: a powerful approach to lithium ion dynamics in solid-state electrolytes"

M. Graf, B. Kresse, A. F. Privalov, M. Vogel Solid State Nucl. Magn. Reson. 2013, 51, 25–30

"Dynamics of the ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethylsulphonyl)imide studied by nuclear magnetic resonance dispersion and diffusion"

A. O. Seyedlar, S. Stapf, C. Mattea Phys. Chem. Chem. Phys. 2015, 17, 1653–1659

"Field-cycling NMR relaxometry of viscous liquids and polymers"

D. Kruk, A. Herrmann, E. A. Rössler Prog. Nucl. Magn. Reson. Spectrosc. 2012, 63, 33–64

"Translational dynamics of ionic liquid imidazolium cations at solid/liquid interface in gel polymer electrolyte"

A. Rachocki, E. Andrzejewska, A. Dembna, J. Tritt-Goc Eur. Polym. J. 2015, 71, 210–220

"Translational diffusion in paramagnetic liquids by 1H NMR relaxometry: Nitroxide radicals in solution"

D. Kruk, A. Korpała, A. Kubica, R. Meier, E. A. Rössler, J. Mościcki J. Chem. Phys. 2013, 138, 024506

"Investigation of Dynamics in BMIM TFSA Ionic Liquid through Variable Temperature and Pressure NMR Relaxometry and Diffusometry"

K. Pilar, A. Rua, S. N. Suarez, C. Mallia, S. Lai, J. R. P. Jayakody, J. L. Hatcher, J. F. Wishart, S. J. Greenbaum J. Electrochem. Soc. 2017, 164, H5189–H5196

"Fast field cycling NMR relaxometry studies of molten and cooled cocoa butter"

M. Ladd-Parada, M. J. Povey, J. Vieira, M. E. Ries Mol. Phys. 2018, 1–8

"Water dynamics in eggs by means of Nuclear Magnetic Resonance relaxometry"

D. Kruk, M. Florek-Wojciechowska, M. Oztop, E. Ilhan, Z. Wieczorek J. Magn. Reson. 2021, 327, 106976

"Translational and rotational diffusion of three glass forming alcohols by 1H field cycling NMR relaxometry"

E. Carignani, E. Juszyńska-Gałązka, M. Gałązka, C. Forte, M. Geppi, L. Calucci J. Mol. Liq. 2021, 330, 115597

"Monitoring of engine oils using NMR relaxometry"

E. Förster, C. C. Fraenza, J. Küstner, E. Anoardo, H. Nirschl, G. Guthausen (titolo completo non fornito nei dati disponibili)

Relaxometry and Overhauser Dynamic: Nuclear Polarization

"Field Dependent Dynamic Nuclear Polarization with Radicals in Aqueous Solution"

Höfer P., Parigi G., Luchinat C., Carl P., Guthausen G., Reese M., Carlomagno T., Griesinger C., Bennati M. J. Am. Chem. Soc. 2008, 130, 3254–3255

"Water1H relaxation dispersion analysis on a nitroxide radical provides information on the maximal signal enhancement in Overhauser dynamic nuclear polarization experiments"

Bennati M., Luchinat C., Parigi G., Türke M.-T. Phys. Chem. Chem. Phys. 2010, 12, 5902–5910

"Liquid state DNP of water at 9.2 T: an experimental access to saturation"

Neugebauer P., Krummenacker J. G., Denysenkov V. P., Parigi G., Luchinat C., Prisner T. F. Phys. Chem. Chem. Phys. 2013, 15, 6049–6056

"Perspectives on paramagnetic NMR from a life sciences infrastructure"

Ravera E., Luchinat C., Parigi G. J. Magn. Reson. 2016, 264, 78–87

"One-thousand fold enhancement of high field liquid nuclear-magnetic resonance signals at room temperature"

Liu G., Levien M., Karschin N., Parigi G., Luchinat C., Bennati M. Nat. Chem. 2017, 9, 676–680

"Field-cycling NMR and DNP–A friendship with benefits"

Gizatullin B., Mattea C., Stapf S. J. Magn. Reson. 2021, 322, 106851

"Overhauser DNP FFC study of block copolymer diluted solution"

Gizatullin B., Mattea C., Stapf S. Magn. Reson. Imaging 2019, 56, 96–102

"Molecular dynamics-based selectivity for Fast-Field-Cycling relaxometry by Overhauser and solid effect dynamic nuclear polarization"

Neudert O., Mattea C., Stapf S. J. Magn. Reson. 2017, 276, 113–121

"Dynamic nuclear polarization NMR fast field cycling study complex systems"

Gizatullin B. PhD Thesis, TU Ilmenau 2020

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